油气田开发

低渗透储集层表面活性剂胶束溶液助排机理

  • 李俊键 ,
  • 刘奔 ,
  • 郭成 ,
  • 苏航 ,
  • 于馥玮 ,
  • 马梦琪 ,
  • 王利达 ,
  • 姜汉桥
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  • 1.油气资源与探测国家重点实验室(中国石油大学(北京)),北京 102249;
    2.中国石油勘探开发研究院,北京 100083
李俊键(1983-),男,山东青州人,博士,中国石油大学(北京)石油工程学院教授,主要从事油气渗流机理及提高采收率方面的研究。地址:北京市昌平区府学路18号,中国石油大学(北京)石油工程学院,邮政编码:102249。E-mail:junjian@cup.edu.cn

收稿日期: 2021-07-27

  网络出版日期: 2022-03-16

基金资助

国家科技重大专项(2017ZX05009-005-003); 中国石油大学(北京)科研基金(2462019QNXZ04)

Mechanisms of water block removal by surfactant micellar solutions in low permeability reservoirs

  • LI Junjian ,
  • LIU Ben ,
  • GUO Cheng ,
  • SU Hang ,
  • YU Fuwei ,
  • MA Mengqi ,
  • WANG Lida ,
  • JIANG Hanqiao
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  • 1. State Key Laboratory of Petroleum Resources and Prospecting, China University of Petroleum, Beijing 102249, China;
    2. Research Institute of Petroleum Exploration & Development, PetroChina, Beijing 100083, China

Received date: 2021-07-27

  Online published: 2022-03-16

摘要

鉴于针对表面活性剂胶束溶液的研究仍以配方优化和岩心实验为主,且适用于低渗透储集层的助排剂类型及其助排机理尚不明确的现状,在通过岩心实验评价不同类型表面活性剂胶束溶液助排效率的基础上,研制了表征低渗透储集层孔喉结构的多级孔喉系统微观模型,分别开展了盐水及不同盐度表面活性剂胶束溶液在微观模型中的返排实验,直观呈现了表面活性剂胶束溶液作用下微米级孔隙中原油返排的过程,揭示了表面活性剂胶束溶液的助排机理。研究表明,盐水和低盐度表面活性剂胶束溶液驱替及返排过程中均会产生大量小液滴,小液滴通过孔喉时因贾敏效应产生巨大的渗流阻力,导致驱替、返排压差的升高和驱油、返排效率的降低;能够与原油混溶形成Winsor Ⅲ型微乳液的临界盐度和最佳盐度表面活性剂胶束溶液则不会产生大量阻碍流动的小液滴,能够有效降低渗流阻力,提高驱油及返排效率。

本文引用格式

李俊键 , 刘奔 , 郭成 , 苏航 , 于馥玮 , 马梦琪 , 王利达 , 姜汉桥 . 低渗透储集层表面活性剂胶束溶液助排机理[J]. 石油勘探与开发, 2022 , 49(2) : 348 -357 . DOI: 10.11698/PED.2022.02.13

Abstract

The existing researches on surfactant micellar solutions mainly focus on the formulation optimization and core flooding test, and the types and mechanisms of cleanup additives suitable for low permeability reservoir remain unclear. The flowback efficiencies of different types of surfactant micellar solutions were evaluated by core experiments, a multi-level pore-throat system micromodel characterizing pore-throat structures of low permeability reservoir was made, and flooding and flowback experiments of brine and surfactant micellar solutions of different salinities were conducted with the micromodel to show the oil flowback process in micron pores under the effect of surfactant micellar solution visually and reveal the mechanisms of enhancing displacement and flowback efficiency of surfactant micellar solution. During the displacement and flowback of brine and low salinity surfactant micellar solution, many small droplets were produced, when the small droplets passed through pore-throats, huge percolation resistance was created due to Jamin’s effect, leading to the rise of displacement and flowback pressure differences and the drop of flowback efficiency. The surfactant micellar solutions with critical salinity and optimal salinity that were miscible with crude oil to form Winsor Ⅲ micro-emulsion didnot produce mass small droplets, so they could effectively reduce percolation resistance and enhance oil displacement and flowback efficiency.

参考文献

[1] HOLDITCH S A. Factors affecting water blocking and gas flow from hydraulically fractured gas wells[J]. Journal of Petroleum Technology, 1979, 31(12): 1515-1524.
[2] LE D H, HOANG H N, MAHADEVAN J. Gas recovery from tight sands: Impact of capillarity[J]. SPE Journal, 2012, 17(4): 981-991.
[3] MAHADEVAN J, SHARMA M M, YORTSOS Y C. Capillary wicking in gas wells[J]. SPE Journal, 2007, 12(4): 429-437.
[4] ABRAMS A, VINEGAR H J. Impairment mechanisms in Vicksburg tight gas sands[R]. SPE 13883-MS, 1985.
[5] PAREKH B, SHARMA M M. Cleanup of water blocks in depleted low-permeability reservoirs[R]. SPE 89837-MS, 2004.
[6] 朱维耀, 岳明, 刘昀枫, 等. 中国致密油藏开发理论研究进展[J]. 工程科学学报, 2019, 41(9): 1103-1114.
ZHU Weiyao, YUE Ming, LIU Yunfeng, et al. Research progress on tight oil exploration in China[J]. Chinese Journal of Engineering, 2019, 41(9): 1103-1114.
[7] 梁天博, 马实英, 魏东亚, 等. 低渗透油藏水锁机理与助排表面活性剂的优选原则[J]. 石油学报, 2020, 41(6): 745-752.
LIANG Tianbo, MA Shiying, WEI Dongya, et al. Water blocking mechanism of low-permeability reservoirs and screening principle of flowback surfactants[J]. Acta Petrolei Sinica, 2020, 41(6): 745-752.
[8] 曾凡辉, 张蔷, 郭建春, 等. 页岩水化及水锁解除机制[J]. 石油勘探与开发, 2021, 48(3): 646-653.
ZENG Fanhui, ZHANG Qiang, GUO Jianchun, et al. Mechanisms of shale hydration and water block removal[J]. Petroleum Exploration and Development, 2021, 48(3): 646-653.
[9] LIANG T B, ZHOU F J, LU J, et al. Evaluation of wettability alteration and IFT reduction on mitigating water blocking for low-permeability oil-wet rocks after hydraulic fracturing[J]. Fuel, 2017, 209: 650-660.
[10] SHENG J J. Critical review of field EOR projects in shale and tight reservoirs[J]. Journal of Petroleum Science and Engineering, 2017, 159: 654-665.
[11] HE K, XU L, GAO Y F, et al. Evaluation of surfactant performance in fracturing fluids for enhanced well productivity in unconventional reservoirs using Rock-on-a-Chip approach[J]. Journal of Petroleum Science and Engineering, 2015, 135: 531-541.
[12] BUI K, AKKUTLU I Y, ZELENEV A, et al. Insights into mobilization of shale oil by use of microemulsion[J]. SPE Journal, 2016, 21(2): 613-620.
[13] SHULER P J, LU Z, MA Q S, et al. Surfactant huff-n-puff application potentials for unconventional reservoirs[R]. SPE 179667-MS, 2016.
[14] LONGORIA R A, LIANG T B, HUYNH U T, et al. Water blocks in tight formations: The role of matrix/fracture interaction in hydrocarbon-permeability reduction and its implications in the use of enhanced oil recovery techniques[J]. SPE Journal, 2017, 22(5): 1393-1401.
[15] LIANG T B, SHAO L J, YAO E D, et al. Study on fluid-rock interaction and reuse of flowback fluid for gel fracturing in desert area[J]. Geofluids, 2018, 2018: 8948961.
[16] LIANG T B, LONGORIA R A, LU J, et al. Enhancing hydrocarbon permeability after hydraulic fracturing: Laboratory evaluations of shut-ins and surfactant additives[J]. SPE Journal, 2017, 22(4): 1011-1023.
[17] LIANG T B, LUO X, NGUYEN Q, et al. Computed-tomography measurements of water block in low-permeability rocks: Scaling and remedying production impairment[J]. SPE Journal, 2018, 23(3): 762-771.
[18] LIANG T B, XU K, LU J, et al. Evaluating the performance of surfactants in enhancing flowback and permeability after hydraulic fracturing through a microfluidic model[J]. SPE Journal, 2020, 25(1): 268-287.
[19] LUO P, LI S, KNORR K D, et al. Underlying mechanisms of tight reservoir wettability and its alteration[R]. SPE 190214-MS, 2018.
[20] ZHANG D L, QI C Y, SHI X D, et al.Evaluation of relative permeability of a tight oil formation in Daqing Oilfield[R].SPWLA 2021-0075, 2021.
[21] 张永超. 致密砂岩中的润湿性及其对石油运移和聚集的影响研究[D]. 北京: 中国石油大学(北京), 2019.
ZHANG Yongchao. The wettability in tight sandstone formations and its effects on oil migration and accumulation[D]. Beijing: China University of Petroleum (Beijing), 2019.
[22] 廖玉梅. 鄂尔多斯盆地延长组致密砂岩润湿性及其油气成藏意义[D]. 北京: 中国石油大学(北京), 2016.
LIAO Yumei. The wettability of tight sandstone and its significance of hydrocarbon accumulation of Yanchang Formation, Ordos Basin[D]. Beijing: China University of Petroleum (Beijing), 2016.
[23] YU F W, JIANG H Q, MA M Q, et al. Visualization the surfactant imbibition at pore scale by using of fractured micromodels[R]. SPE 200349-MS, 2020.
[24] 于馥玮, 高振东, 朱文浩, 等. 基于微流控模型的裂缝性储集层渗吸机理实验[J]. 石油勘探与开发, 2021, 48(5): 1004-1013.
YU Fuwei, GAO Zhendong, ZHU Wenhao, et al. Experimental research on imbibition mechanisms of fractured reservoirs by microfluidic chips[J]. Petroleum Exploration and Development, 2021, 48(5): 1004-1013.
[25] YU F W, JIANG H Q, FAN Z, et al. Formation and flow behaviors of in situ emulsions in heavy oil reservoirs[J]. Energy & Fuels, 2019, 33(7): 5961-5970.
[26] XU K, LIANG T B, ZHU P X, et al. A 2.5-D glass micromodel for investigation of multi-phase flow in porous media[J]. Lab on a Chip, 2017, 17(4): 640-646.
[27] 于馥玮, 姜汉桥, 范桢, 等. 油湿多孔介质中Winsor Ⅰ型表面活性剂体系特征及渗吸机理[J]. 石油勘探与开发, 2019, 46(5): 950-958.
YU Fuwei, JIANG Hanqiao, FAN Zhen, et al. Features and imbibition mechanisms of Winsor Ⅰ type surfactant solution in oil-wet porous media[J]. Petroleum Exploration and Development, 2019, 46(5): 950-958.
[28] 李俊键, 苏航, 姜汉桥, 等. 微流控模型在油气田开发中的应用[J]. 石油科学通报, 2018, 3(3): 284-301.
LI Junjian, SU Hang, JIANG Hanqiao, et al. Application of microfluidic models in oil and gas field development[J]. Petroleum Science Bulletin, 2018, 3(3): 284-301.
[29] YU F W, JIANG H Q, XU F, et al. New insights into flow physics in the EOR process based on 2.5D reservoir micromodels[J]. Journal of Petroleum Science and Engineering, 2019, 181: 106214.
[30] TAGAVIFAR M, XU K, JANG S H, et al. Spontaneous and flow- driven interfacial phase change: Dynamics of microemulsion formation at the pore scale[J]. Langmuir, 2017, 33(45): 13077-13086.
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