油气勘探

四川盆地超深层天然气地球化学特征

  • 戴金星 ,
  • 倪云燕 ,
  • 秦胜飞 ,
  • 黄士鹏 ,
  • 彭威龙 ,
  • 韩文学
展开
  • 中国石油勘探开发研究院,北京 100083
戴金星(1935-),男,浙江温州人,中国科学院院士,中国石油勘探开发研究院教授级高级工程师,从事天然气地质与地球化学方面的研究工作。地址:北京市海淀区学院路20号,中国石油勘探开发研究院院部,邮政编码:100083。E-mail: djx@petrochina.com.cn

收稿日期: 2018-04-18

  修回日期: 2018-05-08

  网络出版日期: 2018-06-13

基金资助

国家油气科技重大专项(2016ZX05007-001); 中国石油天然气股份有限公司科技管理部项目(2014B-0608)

Geochemical characteristics of ultra-deep natural gas in the Sichuan Basin, SW China

  • DAI Jinxing ,
  • NI Yunyan ,
  • QIN Shengfei ,
  • HUANG Shipeng ,
  • PENG Weilong ,
  • HAN Wenxue
Expand
  • Research Institute of Petroleum Exploration & Development, PetroChina, Beijing 100083

Received date: 2018-04-18

  Revised date: 2018-05-08

  Online published: 2018-06-13

摘要

对四川盆地38口井超深层(埋深大于6 000 m)天然气组分及其地球化学特征进行分析,以判明超深层天然气成因。四川盆地超深层天然气组分具如下特征:甲烷占绝对优势,含量最高达99.56%,平均86.67%;乙烷含量低,平均为0.13%;几乎没有丙、丁烷,为干气,属过成熟度气。硫化氢含量最高为25.21%,平均为5.45%;烷烃气碳同位素组成为:δ13C1值从-33.6‰变化至-26.7‰,δ13C2值从-32.9‰变化至-22.1‰,绝大部分没有倒转而主要为正碳同位素组成系列。烷烃气氢同位素组成为:δD1值从-156‰变化至-113‰,少量井δD2值从-103‰变化至-89‰。二氧化碳碳同位素组成为:δ13CCO2值从-17.2‰变化至1.9‰,绝大部分在0±3‰范围。根据δ13C1-δ13C2-δ13C3鉴别图版,盆地超深层烷烃气除个别井外绝大部分为煤成气。根据二氧化碳成因鉴别图和δ13CCO2值,判定除个别井外,超深层二氧化碳绝大部分为碳酸盐岩变质成因。龙岗气田和元坝气田超深层硫化氢为非生物还原型(热化学硫酸盐还原成因),双探号井的超深层硫化氢可能为裂解型(硫酸盐热裂解成因)。图8表1参74

本文引用格式

戴金星 , 倪云燕 , 秦胜飞 , 黄士鹏 , 彭威龙 , 韩文学 . 四川盆地超深层天然气地球化学特征[J]. 石油勘探与开发, 2018 , 45(4) : 588 -597 . DOI: 10.11698/PED.2018.04.05

Abstract

The natural gas components and geochemistry of 50 ultra-deep gas wells (buried depth greater than 6000 m) in the Sichuan Basin were analyzed to determine the genesis of ultra-deep natural gas in the basin. The natural gas components of the basin have the following characteristics: Methane has an absolute advantage, which can be up to 99.56% with an average of 86.6%; ethane is low, with an average of 0.13%; there is nearly no propane and butane. So it is dry gas at over-mature thermal stage. The content of H2S can be up to 25.21%, with an average of 5.45%. The alkane gas isotopes are: The carbon isotope varies from -32.3‰ to -26.7‰ for methane and from -32.9‰ to -22.1‰ for ethane. There is nearly no carbon isotopic reversal among methane and its homologues. Hydrogen isotope varies from -156‰ to -114‰ for methane, and from -103‰ to -89‰ for some ethane. The carbon isotope of CO2 varies from -17.2‰ to 1.9‰ and most of them fall within the range of 0±3‰. According to the δ13C1-δ13C2-δ13C3 plot, except some wells, all other ultra-deep gas wells are dominated by coal-derived gas. Based on the CO2 origin distinguishing plot and δ13CCO2, except individual wells, most of the ultra-deep CO2 are of carbonate metamorphic origin. H2S in the ultra-deep layer of Longgang and Yuanba gas fields belongs to thermochemical sulfate reduction (TSR), while H2S from Well Shuangtan belongs to thermal decomposition of sulfides (TDS).

参考文献

[1] 中华人民共和国国土资源部. 石油天然气储量计算规范: DZ/T 0217—2005[S]. 北京: 中国标准出版社, 2005.
Ministry of Natural Resources of the People’s Republic of China. Specification for the calculation of oil and gas reserves: DZ/T 0217—2005[S]. Beijing: China Standards Press, 2005.
[2] 史斗, 刘文汇, 郑军卫. 深层气理论分析和深层气潜势研究[J]. 地球科学进展, 2003, 18(2): 236-244.
SHI Dou, LIU Wenhui, ZHENG Junwei.Theory analysis on deep seated gas and its potential study[J]. Advance in Earth Sciences, 2003, 18(2): 236-244.
[3] 李小地. 中国深部油气藏的形成与分布初探[J]. 石油勘探与开发, 1994, 21(1): 34-39.
LI Xiaodi.Formation and distribution of deep oil and gas reservoirs in China[J]. Petroleum Exploration and Development, 1994, 21(1): 34-39.
[4] 妥进才, 王先彬, 周世新, 等. 深层油气勘探现状与研究进展[J]. 天然气地球科学, 1999, 10(6): 1-8.
TUO Jincai, WANG Xianbin, ZHOU Shixin, et al.Exploration status and research progress of deep oil and gas[J]. Natural Gas Geoscience, 1999, 10(6): 1-8.
[5] 刘文汇, 郑建京, 妥进才, 等. 塔里木盆地深层气[M]. 北京: 科学出版社, 2007: 1-3.
LIU Wenhui, ZHENG Jianjing, TUO Jincai, et al.Deep gas reservoir of Tarim Basin[M]. Beijing: Science Press, 2007: 1-3.
[6] SAMVELOV R G.Features of hydrocarbon pools formation at depths[J]. Oil and Gas Geology, 1995(9): 5-15.
[7] 戴金星, 丁巍伟, 侯路, 等. 松辽盆地深层气勘探和研究[C]//贾承造. 松辽盆地深层天然气勘探研讨会报告集. : 石油工业出版社, 2004: 27-44.
DAI Jinxing, DING Weiwei, HOU Lu, et al.Deep gas exploration and research in Songliao Basin[C]//JIA Chengzao. Proceedings of Symposium on Deep Gas Exploration in Songliao Basin. Beijing: Petroleum Industry Press, 2004: 27-44.
[8] 中国石油学会. 深层油气地质学科发展报告[M]. 北京: 中国科学技术出版社, 2016: 5-6.
Chinese Petroleum Society.Report on advances in deep petroleum geology discipline[M]. Beijing: Science and Technology of China Press, 2016: 5-6.
[9] 侯启军, 杨玉峰. 松辽盆地无机成因天然气及勘探方向探讨[J]. 天然气工业, 2002, 22(3): 5-10.
HOU Qijun, YANG Yufeng.Abiogenetic natural gases in Songliao Basin and their exploration prospects[J]. Natural Gas Industry, 2002, 22(3): 5-10.
[10] 陈墨香. 华北地热[M]. 北京: 科学出版社, 1988: 24-31.
CHEN Moxiang.Geothermal in north China[M]. Beijing: Science Press, 1988: 24-31.
[11] 冯昌格, 刘绍文, 王良书, 等. 塔里木盆地现今地热特征[J]. 地球物理学报, 2009, 52(11): 2752-2762.
FENG Changge, LIU Shaowen, WANG Liangshu, et al.Present-day geothermal regime in Tarim Basin, northwest China[J]. Chinese Journal of Geophysics, 2009, 52(11): 2752-2762.
[12] 徐明, 朱传庆, 田云涛, 等. 四川盆地钻孔温度测量及现今地热特征[J]. 地球物理学报, 2011, 54(4): 1052-1060.
XU Ming, ZHU Chuanqing, TIAN Yuntao, et al.Borehole temperature logging and characteristics of subsurface temperature in the Sichuan Basin[J]. Chinese Journal of Geophysics, 2011, 54(4): 1052-1060.
[13] 赵文智, 胡素云, 刘伟, 等. 再论中国陆上深层海相碳酸盐岩油气地质特征与勘探前景[J]. 天然气工业, 2014, 34(4): 1-9.
ZHAO Wenzhi, HU Suyun, LIU Wei, et al.Petroleum geological features and exploration prospect in deep marine carbonate strata onshore China: A further discussion[J]. Natural Gas Industry, 2014, 34(4): 1-9.
[14] 王招明, 李勇, 谢会文, 等. 库车前陆盆地超深层大油气田形成的地质认识[J]. 中国石油勘探, 2016, 21(1): 37-43.
WANG Zhaoming, LI Yong, XIE Huiwen, et al.Geological understanding on the formation of large-scale ultra-deep oil-gas field in Kuqa foreland basin[J]. China Petroleum Exploration, 2016, 21(1): 37-43.
[15] 冯佳睿, 高志勇, 崔京钢, 等. 深层、超深层碎屑岩储集层勘探现状与研究进展[J]. 地球科学进展, 2016, 31(7): 718-736.
FENG Jiarui, GAO Zhiyong, CUI Jinggang, et al.The exploration status and research advances of deep and ultra-deep clastic reservoirs[J]. Advances in Earth Science, 2016, 31(7): 718-736.
[16] 肖德铭, 迟元林, 蒙启安, 等. 松辽盆地北部深层天然气地质特征研究[C]//谯汉生, 罗广斌, 李先奇. 中国东部深层石油勘探论文集. 北京: 石油工业出版社, 2001: 1-27.
XIAO Deming, CHI Yuanlin, MENG Qi’an, et al.Geological characteristics of deep natural gas in the northern Songliao Basin[C]//QIAO Hansheng, LUO Guangbin, LI Xianqi. Symposium of Deep Oil Exploration in Eastern China. Beijing: Petroleum Industry Press, 2001: 1-27.
[17] MIELIENIEXSK V N.About deep zonation of oil/gas formation[J]. Exploration and Protection Minerals, 1999, 11: 42-43.
[18] 何治亮, 金晓辉, 沃玉进, 等. 中国海相超深层碳酸盐岩油气成藏特点及勘探领域[J]. 中国石油勘探, 2016, 20(1): 3-14.
HE Zhiliang, JIN Xiaohui, WO Yujin, et al.Hydrocarbon accumulation characteristics and exploration domains of ultra-deep marine carbonates in China[J]. China Petroleum Exploration, 2016, 20(1): 3-14.
[19] 李忠. 盆地深层流体-岩石作用与油气形成研究前沿[J]. 矿物岩石地球化学通报, 2016, 35(5): 807-816.
LI Zhong.Research frontiers of fluid-rock interaction and oil-gas formation in deep-buried Basins[J]. Bulletin of Mineralogy, Petrology and Geochemistry, 2016, 35(5): 807-816.
[20] 孙玮, 刘树根, 曹俊兴, 等. 四川叠合盆地西部中北段深层—超深层海相大型气田形成条件分析[J]. 岩石学报, 2017, 33(4): 1171-1188.
SUN Wei, LIU Shugen, CAO Junxing, et al.Analysis on the formation conditions of large-scale marine deep and super-deep strata gas fields in the middle-northern segments of western Sichuan Superimposed Basin, China[J]. Acta Petrologica Sinica, 2017, 33(4): 1171-1188.
[21] 戴金星. 我国天然气藏的分布特征[J]. 石油与天然气地质, 1982, 3(3): 270-276.
DAI Jinxing.Distribution characteristics of gas pools in China[J]. Oil & Gas Geology, 1982, 3(3): 270-276.
[22] JEMISON R M.Geology and development of Mills Ranch complex: World’s deepest field[J]. AAPG Bulletin, 1979, 63(5): 804-809.
[23] IHS. IHS energy[DB/OL]. (2007-11-21)[2018-04-01]. https://ihsmarkit.com/country-industry-forecasting.html?ID=106597420.
[24] 苏华, 田崇辉. 超深井如何打出超水平[N]. 中国石油报, 2017-12-07(3).
SU Hua, TIAN Chonghui. How to get out of super level in super deep well[N]. China Petroleum Daily, 2017-12-07(3).
[25] 王宓君, 包茨, 李懋钧, 等. 中国石油地质志(卷十, 四川油气区)[M]. 北京: 石油工业出版社, 1989: 6-9.
WANG Mijun, BAO Ci, LI Maojun, et al.Petroleum geology of China (Vol.10, Sichuan Petroleum Area)[M]. Beijing: Petroleum Industry Press, 1989: 6-9.
[26] 李熙喆, 郭振华, 胡勇, 等. 中国超深层构造型大气田高效开发策略[J]. 石油勘探与开发, 2018, 45(1): 111-118.
LI Xizhe, GUO Zhenhua, HU Yong, et al.Efficient development strategies for large ultra-deep structural gas fields in China[J]. Petroleum Exploration and Development, 2018, 45(1): 111-118.
[27] HU G Y, YU C, GONG D Y, et al.The origin of natural gas and influence on hydrogen isotope of methane by TSR in the Upper Permian Changxing and the Lower Triassic Feixianguan Formations in northern Sichuan Basin, SW China[J]. Energy Exploration & Exploitation, 2014, 32(1): 139-158.
[28] 郭旭升, 郭彤楼. 普光、元坝碳酸盐岩台地边缘大气田勘探理论与实践[M]. 北京: 科学出版社, 2012: 287.
GUO Xusheng, GUO Tonglou.Theory and practice of giant gas fields of carbonate platform margin in Puguang and Yuanba[M]. Beijing: Science Press, 2012: 287.
[29] WU X Q, LIU G X, LIU Q Y, et al.Geochemical characteristics and genetic types of natural gas in the Changxing-Feixianguan Formations from the Yuanba Gas Field in the Sichuan Basin, China[J]. Journal of Natural Gas Geoscience, 2016, 1(4): 267-275.
[30] QIN S F, ZHOU G X, ZHOU Z, et al. Geochemical characteristics of natural gases from different petroleum systems in the Longgang gas field, Sichuan Basin, China[J/OL]. Energy Exploration & Exploitation, 2018, in press.
[31] 戴金星. 天然气中烷烃气碳同位素研究的意义[J]. 天然气工业, 2011, 31(12): 1-6.
DAI Jinxing.Significance of the study on carbon isotopes of alkane gases[J]. Natural Gas Industry, 2011, 31(12): 1-6.
[32] 戴金星. 煤成气及鉴别理论研究进展[J]. 科学通报, 2018, 63(14): 1291-1305.
DAI Jinxing.Coal-derived gas theory and its discrimination (in Chinese)[J]. Chinese Science Bulletin, 2018, 63(14): 1291-1305.
[33] 戴金星, 裴锡古, 戚厚发. 中国天然气地质学(卷一)[M]. 北京: 石油工业出版社, 1992: 37-69.
DAI Jinxing, PEI Xigu, QI Houfa.Natural gas geology in China(Vol.1)[M]. Beijing: Petroleum Industry Press, 1992: 37-69.
[34] BARKER C.Petroleum generation and occurrence for exploration geologists[M]. Berlin: Springer, 1883.
[35] BUCHA M, JEDRYSEK M O, KUFKA D, et al.Methanogenic fermentation of lignite with carbon-bearing additives, inferred from stable carbon and hydrogen isotopes[J]. International Journal of Coal Geology, 2018, 186: 65-79.
[36] 戴金星, 倪云燕, 黄士鹏, 等. 煤成气研究对中国天然气工业发展的重要意义[J]. 天然气地球科学, 2014, 25(1): 1-22.
DAI Jinxing, NI Yunyan, HUANG Shipeng, et al.Significant function of coal-derived gas study for natural gas industry development in China[J]. Natural Gas Geoscience, 2014, 25(1): 1-22.
[37] 赵文智, 徐春春, 王铜山, 等. 四川盆地龙岗和罗家寨—普光地区二、三叠系长兴—飞仙关组礁滩体天然气成藏对比研究与意义[J]. 科学通报, 2011, 56(28/29): 2404-2412.
ZHAO Wenzhi, XU Chunchun, WANG Tongshan, et al.Comparative study of gas accumulations in the Permian Changxing reefs and Triassic Feixianguan oolitic reservoirs between Longgang and Luojiazhai-Puguang in the Sichuan Basin[J]. Chinese Science Bulletin, 2011, 56(31): 3310-3320.
[38] DAI J X, XIA X Y, QIN S F, et al.Origins of partially reversed alkane δ13C values for biogenic gases in China[J]. Organic Geochemistry, 2004, 35(4): 405-411.
[39] NI Y Y, DAI J X, TAO S Z, et al.Helium signatures of gases from the Sichuan Basin, China[J]. Organic Geochemistry, 2014, 74: 33-43.
[40] 戴金星, 邹才能, 李伟, 等. 中国煤成大气田及气源[M]. 北京: 科学出版社, 2014: 197-203.
DAI Jinxing, ZOU Caineng, LI Wei, et al.Giant coal-derived gas fields and their gas sources in China[M]. Beijing: Science Press, 2014: 197-203.
[41] 郭旭升, 黄仁春, 付孝悦, 等. 四川盆地二叠系和三叠系礁滩天然气富集规律与勘探方向[J]. 石油与天然气地质, 2014, 35(3): 295-302.
GUO Xusheng, HUANG Renchun, FU Xiaoyue, et al.Gas accumulation and exploration direction of the Permian and Triassic reservoirs of reef-bank facies in Sichuan Basin[J]. Oil & Gas Geology, 2014, 35(3): 295-302.
[42] 郭彤楼. 元坝深层礁滩气田基本特征与成藏主控因素[J]. 天然气工业, 2011, 31(10): 1-5.
GUO Tonglou.Basin characteristics of deep reef-bank reservoirs and major controlling factors of gas pools in the Yuanba gas field[J]. Natural Gas Industry, 2011, 31(10): 1-5.
[43] LI P P, HAO F, GUO X S, et al.Processes involved in the origin and accumulation of hydrocarbon gases in the Yuanba gas field, Sichuan Basin, southwest China[J]. Marine & Petroleum Geology, 2015, 59(1): 150-165.
[44] 朱扬明, 顾圣啸, 李颖, 等. 四川盆地龙潭组高热演化烃源岩有机质生源及沉积环境探讨[J]. 地球化学, 2012, 41(1): 35-44.
ZHU Yangming, GU Shengxiao, LI Ying, et al.Biological organic source and depositional environment of over-mature source rocks of Longtan Formation in Sichuan Basin[J]. Geochimica, 2012, 41(1): 35-44.
[45] 黄福喜, 杨涛, 闫伟鹏, 等. 四川盆地龙岗与元坝地区礁滩成藏对比分析[J]. 中国石油勘探, 2014, 19(3): 12-20.
HUANG Fuxi, YANG Tao, YAN Weipeng, et al.Comparison and analysis of reef-bank gas reservoirs in Longgang and Yuanba areas in Sichuan Basin[J]. China Petroleum Exploration, 2014, 19(3): 12-20.
[46] 仵宗涛, 刘兴旺, 李孝甫, 等. 稀有气体同位素在四川盆地元坝气藏气源对比中的应用[J]. 天然气地球科学, 2017, 28(7): 1072-1077.
WU Zongtao, LIU Xingwang, LI Xiaofu, et al.The application of noble gas isotope in gas-source correlation of Yuanba reservoir, Sichuan Basin[J]. Natural Gas Geoscience, 2017, 28(7): 1072-1077.
[47] REDDING C E, SCHOELL M, MONIN J C, et al.Hydrocarbon and carbon isotope composition of coals and kerogens[J]. Physics & Chemistry of the Earth, 1980, 12(79): 711-723.
[48] 魏国齐, 谢增业, 宋家荣, 等. 四川盆地川中古隆起震旦系—寒武系天然气特征及成因[J]. 石油勘探与开发, 2015, 42(6): 702-711.
WEI Guoqi, XIE Zengye, SONG Jiarong, et al.Features and origin of natural gas in the Sinian-Cambrian of central Sichuan paleo-uplift, Sichuan Basin, SW China[J]. Petroleum Exploration and Development, 2015, 42(6): 702-711.
[49] 王广利, 王铁冠, 韩克猷, 等. 川西北地区固体沥青和油砂的有机地球化学特征与成因[J]. 石油实验地质, 2014, 36(6): 731-735.
WANG Guangli, WANG Tieguan, HAN Keqiu, et al.Organic geochemical characteristics and origin of solid bitumen and oil sands in northwestern Sichuan[J]. Petroleum Geology and Experiment, 2014, 36(6): 731-735.
[50] 饶丹, 秦建中, 腾格尔, 等. 川西北广元地区海相层系油苗和沥青来源分析[J]. 石油实验地质, 2008, 30(6): 596-599.
RAO Dan, QIN Jianzhong, TENGER, et al. Source analysis of oil seepage and bitumen originating from marine layer strata in Guangyuan area, the northwest Sichuan Basin[J]. Petroleum Geology and Experiment, 2008, 30(6): 596-599.
[51] 刘春, 张惠良, 沈安江, 等. 川西北地区泥盆系油砂岩地球化学特征及成因[J]. 石油学报, 2010, 31(2): 253-258.
LIU Chun, ZHANG Huiliang, SHEN Anjiang, et al.Geochemistry characteristics and origin of the Devonian oil-sandstone in the northwest of Sichuan Basin[J]. Acta Petrolei Sinica, 2010, 31(2): 253-258.
[52] 周文, 邓虎成, 丘东洲, 等. 川西北天井山构造泥盆系古油藏的发现及意义[J]. 成都理工大学学报(自然科学版), 2007, 34(4): 413-417.
ZHOU Wen, DENG Hucheng, QIU Dongzhou, et al.The discovery and significance of the Devonian paleo-reservoir in Tianjingshan structure of the Northwest Sichuan, China[J]. Journal of Chengdu University of Technology (Science & Technology Edition), 2007, 34(4): 413-417.
[53] 邓虎成, 周文, 丘东洲, 等. 川西北天井山构造泥盆系油砂成矿条件与资源评价[J]. 吉林大学学报(地球科学版), 2008, 38(1): 69-75.
DENG Hucheng, ZHOU Wen, QIU Dongzhou, et al.Oil sand-forming conditions and evaluation on resource of oil sand in Tianjingshan structure in northwest part of Sichuan Basin[J]. Journal of Jilin University (Earth Science Edition), 2008, 38(1): 69-75.
[54] 腾格尔, 秦建中, 付小东, 等. 川西北地区海相油气成藏物质基础: 优质烃源岩[J]. 石油实验地质, 2008, 30(5): 478-483.
TENGER, QIN Jianzhong, FU Xiaodong, et al.Basic conditions of marine hydrocarbon accumulation in northwest Sichuan basin: High quality source rocks[J]. Petroleum Geology and Experiment, 2008, 30(5): 478-483.
[55] 沈平, 徐永昌, 王先彬, 等. 气源岩和天然气地球化学特征及成气机理研究[M]. 兰州: 甘肃科学技术出版社, 1991: 120-121.
SHEN Ping, XU Yongchang, WANG Xianbin, et al.Studies on geochemical characteristics of gas-source rock and natural gas and mechanism of genesis of gas[M]. Lanzhou: Gansu Science and Technology Press, 1991: 120-121.
[56] 上官志冠, 张培仁. 滇西北地区活动断层[M]. 北京: 地质出版社, 1990: 162-164.
SHANGGUAN Zhiguan, ZHANG Peiren.Active faults in Northwestern Yunnan[M]. Beijing: Geological Publishing House, 1990: 162-164.
[57] MOORE J G, BATCHELDER J N, CUNNINGHAM C G.CO2-filled vesicles in mid-ocean basalt[J]. Journal of Volcanology & Geothermal Research, 1977, 2(4): 309-327.
[58] GOLD T, SOTER S.Abiogenic methane and the origin of petroleum[J]. Energy Exploration & Exploitation, 1981, 1(2): 89-103.
[59] 戴金星, 宋岩, 戴春森, 等. 中国东部无机成因气及其气藏形成条件[M]. 北京: 科学出版社, 1995: 17-20.
DAI Jinxing, SONG Yan, DAI Chunsen, et al.Conditions governing the formation of abiogenic gas and gas pools in Eastern China[M]. Beijing: Science Press, 1995: 17-20.
[60] 戴金星. 中国含硫化氢的天然气分布特征、分类及其成因探讨[J]. 沉积学报, 1985, 3(4): 109-120.
DAI Jinxing.Distribution, classification and origin of natural gas with hydrogen sulphide in China[J]. Acta Sedimentologica Sinica, 1985, 3(4): 109-120.
[61] MACHEL H G, FOGHT J.Products and depth limits of microbial activity in petroliferous subsurface setting[M]. Berlin: Springer, 2000: 105-120.
[62] MACHEL H G.Bacterial and thermochemical sulfate reduction in diagenetic settings: Old and new insights[J]. Sedimentary Geology, 2001, 140(1/2): 143-175.
[63] ORR W L.Geologic and geochemical controls on the distribution of hydrogen sulfide in natural gas[J]. Advances in Organic Geochemistry, 1977: 571-597.
[64] WORDEN R H, SMALLEY P C.H2S-producing reactions in deep carbonate gas reservoirs: Khuff Formation, Abu Dhabi[J]. Chemical Geology, 1996, 133(1/2/3/4): 157-171.
[65] MACHEL H G.Gas souring by thermochemical sulfate reduction at 140 ℃: Discussion[J]. AAPG Bulletin, 1998, 82(10): 1870-1873.
[66] 蔡春芳. 有机硫同位素组成应用于油气来源和演化研究进展[J]. 天然气地球科学, 2018, 29(2): 159-167.
CAI Chunfang.Application of organic sulfur isotopic composition to petroleum origin and evolution: A review[J]. Natural Gas Geoscience, 2018, 29(2): 159-167.
[67] 蔡春芳, 赵龙. 热化学硫酸盐还原作用及其对油气与储集层的改造作用: 进展与问题[J]. 矿物岩石地球化学通报, 2016, 35(5): 851-859.
CAI Chunfang, ZHAO Long.Thermochemical sulfate reduction and its effects on petroleum composition and reservoir quality: Advances and problems[J]. Bulletin of Mineralogy, Petrology and Geochemistry, 2016, 35(5): 851-859.
[68] 郭旭升, 郭彤楼, 黄仁春, 等. 四川盆地元坝大气田的发现与勘探[J]. 海相油气地质, 2014, 19(4): 57-64.
GUO Xusheng, GUO Tonglou, HUANG Renchun, et al.Yuanba gas field in Sichuan Basin[J]. Marine Origin Petroleum Geology, 2014, 19(4): 57-64.
[69] 李志生, 李谨, 王东良, 等. 四川盆地含硫化氢气田天然气地球化学特征[J]. 石油学报, 2013, 34(Supp. 1): 84-91.
LI Zhisheng, LI Jin, WANG Dongliang, et al.Geochemical characteristics of natural gas in H2S-bearing gas fields in Sichuan Basin[J]. Acta Petrolei Sinica, 2013, 34(Supp. 1): 84-91.
[70] 朱光有, 张水昌, 马永生, 等. TSR(H2S)对石油天然气工业的积极性研究: H2S的形成过程促进储层次生孔隙的发育[J]. 地学前缘, 2006, 13(3): 141-149.
ZHU Guangyou, ZHANG Shuichang, MA Yongsheng, et al.Effectiveness of thermochemical sulfate reduction on oil and gas industry: A H2S formation accelerating development of the secondary pores in reservoirs[J]. Earth Science Frontiers, 2006, 13(3): 141-149.
[71] 朱光有, 张水昌, 梁英波, 等. 川东北飞仙关组高含H2S气藏特征与TSR对烃类的消耗作用[J]. 沉积学报, 2006, 24(2): 300-308.
ZHU Guangyou, ZHANG Shuichang, LIANG Yingbo, et al.Characteristics of gas reservoirs with high content of H2S in the Northeastern Sichuan Basin and the consumption of hydrocarbons due to TSR[J]. Acta Sedimentologica Sinica, 2006, 24(2): 300-308.
[72] ORR W L.Changes in sulfur content and isotopic ratios of sulfur during petroleum maturation: Study of Big Horn Basin Paleozoic oils[J]. AAPG Bulletin, 1974, 58(11): 2295-2318.
[73] AKSENOV A A, ANISIMOT L A.Forecast of the sulphide distribution in subsalt sediments within the Caspian Depression[J]. Soviet Geology, 1982, 10: 46-52.
[74] 侯路, 胡军, 汤军. 中国碳酸盐岩大气田硫化氢分布特征及成因[J]. 石油学报, 2005, 26(3): 26-32.
HOU Lu, HU Jun, TANG Jun.Distribution and genesis of hydrogen sulfide in giant carbonate gas fields of China[J]. Acta Petrolei Sinica, 2005, 26(3): 26-32.
文章导航

/