JIN Xiaofeng
, 2000, 27(3): 1339-0.
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By high temperature and high pressure simulation experiment, the authors studied the hydrocarbon productivity of pollen and algae, it tells us that oil production potential and gas and liquid hydrocarbon production of Pinus are higher than that of Pediastrum and Oscillatoria. ①At their respective maximum temperature in simulation, Pinus has a higher gas-generation rate than Pediastrum and Oscillatoria. Meanwhile, in the gas from Pinus the content and quality of methane are more and better than that from Pediastrum and Oscillatoria. The gas-generation rate of Pinus is 458mL/g, and more than half (51.81%) of the gas is gaseous hydrocarbon, almost being methane. The gas-generation rate of Pediastrum is 373mL/g, of which gaseous hydrocarbons occupy 34.26%, methane 20%, and some others. The gas-generation rate of Oscillatoria is 348mL/g, of which gaseous hydrocarbons occupy 40.42%, methane occupies only 5%. ②In thermal simulation, the liquid-hydrocarbon-generation rate of Pinus is higher than that of Pediastrum and Oscillatoria. The rate is 59.55 mg/g at the first peak temperature and 169.29 mg/g at the second peak temperature, they are 2.8 times of that of Pediastrum and twice of that of Oscillatoria. In addition, lighter hydrocarbon of the pyrolytic oil from Pinus is 67.25%, it is also higher than that from Pediastrum and Oscillatoria. ③The oil-generation potential of Pinus is higher than that of Pediastrum and Oscillatoria. The maximum potential of Pinus is 721.60mg/g, that of Pediastrum is 446.53mg/g, Oscillatoria 541.86mg/g. ④The liquid-hydrocarbon generation-rate curve of Pinus is bimodal, of which the first peak temperature is 260℃, the second 345℃. The inner matters (organs) of Pinus are considered to participate matters in the generation of early immature-low mature oil. Sporopollen is the main source matter for the mature oil.⑤The liquid-hydrocarbon generation-rate curves of Pediastrum and Oscillatoria are unimodal, of which both peak temperatures are 300℃. Peak temperature of Oscillatoria is always lower, Tmax ranges from 383 to 430℃, belonging to early immature-low mature periods. At highest temperature(395℃) in simulation, Tmax increases rapidly to 581℃. So we believed that the product of Oscillatoria is mainly early immature-low mature oil. The liquid-hydrocarbon generation-rate curve of Pediastrum is flat and wide. When simulation temperature is below 280℃, Tmax is below 438℃, the product is early immature-low mature oil; the temperature is between 280-360℃, Tmax is 438-559℃, the product is mature or over-mature oil.